Chromatography is used for which type of compounds?

In thin layer chromatography,a substance moved by a distance of $4 \ cm$,whereas the solvent moved by a distance of $5 \ cm$. Then the value of retardation factor $(R_f)$ is

The principle of column chromatography is

Match the type of mixture of compounds in Column-$I$ with the technique of separation/purification given in Column-$II$.

Column-$I$	Column-$II$
$A$. Two solids which have different solubilities in a solvent and which do not undergo reaction when dissolved in it	$1$. Crystallisation
$B$. Liquid that decomposes at its boiling point	$2$. Distillation under reduced pressure
$C$. Steam volatile liquid	$3$. Steam distillation
$D$. Two liquids which have boiling points close to each other	$4$. Fractional distillation
$E$. Two liquids with large difference in boiling points	$5$. Simple distillation

State whether the following statements regarding fractional distillation are True or False:
$(i)$ The freezing of vapour of a liquid with a high boiling point takes place first.
$(ii)$ In the column,the more volatile liquid is present in a higher concentration in the vapour phase at higher levels.
$(iii)$ The condensed liquid flows down and provides heat to the vaporizing liquid.
$(iv)$ The liquid with the highest boiling point reaches the top of the column.

The mixture of compounds $A$ and $B$ is passed through a column of $Al_2O_3$ by using alcohol as eluant. Compound $A$ is eluted in preference to compound $B$. Which of the compounds $A$ or $B$ is more readily adsorbed on the column?